Ammonium Chloride

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Ammonium chloride is an inorganic compound with the formula NH4Cl and a white crystalline salt that is highly soluble in water. Solutions of ammonium chloride are mildly acidic. The mineral is commonly formed on burning coal dumps from the condensation of coal-derived gases. It is also found around some types of volcanic vents. It is mainly used as fertilizer and a flavoring agent in some types of liquorice. It is the product from the reaction of hydrochloric acid and ammonia.

Molar mass 53.49 g·mol−1
Appearance White solid, hygroscopic
Odor Odorless
Density 1.519 g/cm3[1]
Melting point 338 °C (640 °F; 611 K) decomposes, sublimes[1]
Boiling point 520 °C (968 °F; 793 K)
Sublimes at 337.6 °C[2]
ΔsublHo = 176.1 kJ/mol[3]
244 g/L (−15 °C)
294 g/L (0 °C)
383.0 g/L (25 °C)
454.4 g/L (40 °C)
740.8 g/L (100 °C)[4]
30.9 (395 g/L)[5]
Solubility Soluble in liquid ammonia, hydrazine,
Slightly soluble in acetone
Insoluble in diethyl ether, ethyl acetate[2]
Solubility in methanol 32 g/kg (17 °C)
33.5 g/kg (19 °C)
35.4 g/kg (25 °C)[2]
Solubility in ethanol 6 g/L (19 °C)[6]
Solubility in glycerol 97 g/kg[2]
Solubility in sulfur dioxide 0.09 g/kg (0 °C)
0.031 g/kg (25 °C)[2]
Solubility in acetic acid 0.67 g/kg (16.6 °C)[2]
Vapor pressure 133.3 Pa (160.4 °C)[7]
6.5 kPa (250 °C)
33.5 kPa (300 °C)[6]
Acidity (pKa) 9.24
-36.7·10−6 cm3/mol[8]
1.642 (20 °C)[2]

 

MATERIAL SAFETY DATA SHEET